Reactions between Azolium Salts and Nucleophilic Reagents. I. Bromo-1,2,3-Triazolium Salts as Brominating Reagents.
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منابع مشابه
Aminodifluorosulfinium Tetrafluoroborate Salts as Stable and Crystalline Deoxofluorinating Reagents
Aminodifluorosulfinium tetrafluoroborate salts were found to act as efficient deoxofluorinating reagents when promoted by an exogenous fluoride source and, in most cases, exhibited greater selectivity by providing less elimination byproduct as compared to DAST and Deoxo-Fluor. Aminodifluorosulfinium tetrafluoroborates are easy handled crystalline salts that show enhanced thermal stability over ...
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BACKGROUND Although the nucleophilic difluoromethylation of aldehydes, ketones, and imines has been realized with PhSO(2)CF(2)H and related reagents, there are still no reports on the enantioselective nucleophilic reactions. RESULTS With a chiral quaternary ammonium salt as the catalyst and KOH as the base, we describe the first enantioselective difluoromethylation of aromatic aldehydes with ...
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Organic phosphonium salts have served as important intermediates in synthetic chemistry. But the use of a substituent on the positive phosphorus as a nucleophile to construct C-C bond remains a significant challenge. Here we report an efficient transition-metal-free protocol for the direct nucleophilic arylation of carbonyls and imines with tetraarylphosphonium salts in the presence of caesium ...
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BACKGROUND In order to increase the effectiveness of cancer treatment, new compounds with potential anticancer activities are synthesized and screened. Here we present the screening of a new class of compounds, 1-(2-picolyl)-, 4-(2-picolyl)-, 1-(2-pyridyl)-, and 4-(2-pyridyl)-3-methyl-1,2,3-triazolium salts and 'parent' 1,2,3-triazole precursors. METHODS Cytotoxic activity of new compounds wa...
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wvhich aire occupied by illustrations, hut the author has Nvritten succinctly without alnyloss of clarity, ani(d he can coinveymnuch valuable information in very little space. H-lis illustrations halve been chosen wisely, and their quality is of a remarkably high standard. There is no notable omission, withi the single exception, perhaps, of an account of the important changes in the only pa-t ...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1969
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.23-2733